Normally, decals are applied to a gloss surface anyway. This is for two main reasons, (1) to reduce silvering (air bubbles trapped between the decal and a flat-painted surface) and (2) to help decal setting solvents make the decal conform. Flat-painted surfaces create drag. When the decal solvent is applied, the decal wrinkles, but smooths out as it dries. If the surface isn't glossed, it may cause the decal to hang, causing wrinkles to remain after it's dry.
In your case, I'd suspect that the gloss area around the decals isn't from the solvent itself, but from glue residue from the decal/paper. You should be able to remove or reduce it using a damp swab.
The normal procedure is to apply a flat coat over the decal after it has dried. This has the added benefit of providing a uniform overall surface so that when you apply your weathering, it behaves the same way over both the decals and the surrounding paint work.