If you're talking about Walther's Solv-a-Set, the only thing you might be doing wrong is using it straight from the bottle, which is extremely potent and will attack the decal aggressively! Mix a 60% solution (60% Solv-a-Set, 40% water), and you should get good and predictable results. Occasionally, you will need to re-coat the decal if it's being uncooperative around surface irregularities.
Solv-a-Set is great stuff, I get great results with it every time.