The grey primer is what I use over bodywork (fillers, etc), but it sands very smoothly and the white should cover just fine. With the Tamiya sprays, I use a method of several mist coats, yes, they will look kind of rough at first, with 15-20 minutes between coats. Then follow up with a couple wet coats to smooth things out and bring up the gloss (remember to wait between coats). I'll polish after about a week of drying time, you can lightly wetsand any orange peel or dust from the paint (600 to 1000 grit), then use the polishing compound of your choice to bring back the gloss. I like to use a piece of flannel as an application, rubbing in small circles, then wiping off the residue. Be careful on the edges, so you don't cut thru the paint and be sure you don't use any polish with wax in it until you're sure you don't have to paint anymore.
Hope this helps some, you can e-mail me if you have further need. Peace!
"Always tell the truth, there's less to remember" Indian Larry