Being someone who uses all sorts of different paints at work (auto restoration), I can say that there are a lot of good questions and answers here. Sounds like your environment was pretty good (spraybooth, humidity level that isnt hateful, etc...).
Always things to think about before you paint:
Have any spray or aerosol products been used in the house (or work area) in the last hour?
Are there any open containers of petroleum based products anywhere near your work area?
How long ago did I spray my last coat?
Is there any more bacon in the fridge?
From the photo, it looks to me like your previous coats were still 'gassing out', meaning that they hadn't fully cured. Most modified and multi component paints have several curing agents and other chemicals that basically need to evaporate for the paint to completely set. If you spray another layer on top, it traps those gasses in, and you get the results that you witnessed, Doog.
I rarely shoot anything glossy with models, but the best bet is that when you decide that the paint has cured long enough, wait one more day.
Hope this info helps.
Steve