Rodu;
The best suggestion I can make is in two parts
1. Practice - Use old figures, plastic army men, or same figure stripped of paint and restart
2. Reference - There are plenty of great "How-To" Books available to assist you
Here are some titles for you to look for.
Building and Painting SCALE FIGURES by Sheperd Paine - Scale Modeling Handbook No. 13 Kalmbach Books - ISBN 0-89024-0690-8
How To Paint Realistic Military Figures by Lynn Kessler and Don Winar - Scale Modeling Handbook No. 14 Kalmbach Books - ISBN 0-89024-125-2
How To Paint Realistic Military Figures by Lynn Kessler and Don Winar - Second Edition Kalmbach Books - ISBN 0-89024-380-8
Painting World War II Miniatures with Mike Davidson - Schiffer Books - ISBN 0-7643-0371-6
Modelling and Painting Figures - Rodrigo Hernandez Cabos - Osprey Modelling Manuals 8 - Osprey Publishing - ISBN 1-902579-23-2
Modelling WWII Figures - Rodrigo Hernandez Cabos - Osprey Modelling Manuals 9 - Osprey Publishing - ISBN 1-84176-137-0
Modelling Waffen-SS Figures - Calvin Tan - Osprey Modelling 23 - Osprey Publishing - ISBN 1-84176-837-5
Modelling Panzer Crewmen of the Heer - Mark J. Bannerman - Osprey Modelling 8 - Osprey Publishing - ISBN 1-84603-132-X
The Verlinden Way Volume V - Francois Verlinden - Verlinden Publications
Focus on Modelling Techniques - Painting & Converting World War Two Figures - Geoff Mills - Almark Modelling Book 13 - Almark Publishing Co. Ltd. ISBN 0-85524-313-9
I hope these help, I have learned many things from each of these so anyone will assist you.
Cheers;
Gregory