To expand on Bill's explanation, both the pink and blue boards use a closed cell foam (finer than the open-cell foam in ordinary foam.
The pink is used in ground contact where high compression strength is required--it crushes at 3200psi. The blue is more for wall insulation and crushes at only 1200psi or so.
As a rule of thumb, the pink is more expensive, but the grain is a bit finer, which can make carving slightly nicer. Now, telling the difference between the pink and the blue is more than passing difficult for a modeler.
Nicely, hot wire cutters make working with either foam very pleasant. They take regular (PVA) glues nicely Polyeurethane glues (aka "Gorilla") can be used, too, but you need weights or wide boards and clamps as that glue expands.
Now, all of the above presumes you are in the US or Canada, in other parts of the world, these foams are refered to by a plethora of other names (Polystyrene in some places) Some of those foams are slightly different chemistries, too.
If you are intending to model water surfaces, you will want a much smoother surface to work upon than the bare foam. Generally a coat of plaster or PVA-soaked tissue paper, then coated in gesso or gel medium, or any of a dozen different techniques.