Enamels or acrylics will brush on just fine. Both acrylics and oils are good for painting figures. Keep in mind that thinning may be necessary to get good, even coverage with a minimum of brush strokes. Because you're brushing, exposures from organic vapors should be essentially a non-issue.
Brands would include:
Testor's enamal and acrylic line
Winsor and Newton for oils.
Tamiya acrylics are pretty fine pigment-wise and may be brushed with some success.
You didn't specify what you were painting, so color recommendations would be rather "iffy".
And welcome to the forum family!
Gip Winecoff