Not sure how the Tamiya primer would react with solvent glue. I think most solvent glues for models are primarily Toluene, and I'm not sure of the compatibility. What I have tried other than MEK was isopropyl alcohol, since that's what I use to thin other Tamiya paints. Isopropyl alcohol and Tamiya primer definitely don't get along, the primer is pretty much instantly turned into something that resembles cottage cheese. MEK is reliable and fairly cheap in comparison to other things. Just have lots of ventilation and don't get it on your skin. Latex gloves are pretty much impervious to it, so they offer good protection. Vinyl gloves, on the other hand, will melt instantly.
Painting a second color over the top of any gloss paint is going to be inviting adhesion and cracking issues, especially if it goes on too thick.
For decanting, I usually get a box of 4 ounce mason jars with lids from somewhere like Amazon. I take one of the lids and drill a big enough hole in the center of it for a 1/4" ID grommet. That lid I use as my decanting lid. Then I take the nozzle off the Tamiya primer can and attach a bendable party straw over the nozzle using epoxy and let that cure overnight. After that, I take the can and shake it for a couple of minutes to get everything in it mixed and ready to spray. Then its just a matter of putting the nozzle/straw assembly back on the can, screwing the lid with the grommet onto one of the mason jars, pushing the straw into the grommet, and spraying all of the paint through the straw into the jar. Don't screw the cap on tightly when doing this, so the propellant can vent. After that, leave the cap loose to allow the propellant to continue to come out of solution. At about 2 hours, carefully stir the paint by hand (no motorized mixers) a little bit at a time...it will boil quickly as the propellant gas continues to come out, so you have to occasionally stop stirring to keep it from boiling over. When it no longer boils when stirred, you can screw the lid on tight and you've got lots of airbrushable Tamiya primer that will be good for weeks or even months of primering model parts.
When airbrushing it, I find it best to put a little bit of the primer into a Dixie paper bathroom cup, and then thin/mix it with MEK. You'll have to stir the primer in the mason jar each time because there is a thick, sticky sludge that settles to the bottom. That sludge is normal though, so don't worry that your primer is drying out. You just have to stir it each time. I usually use a wooden skewer for stirring it since its too thick for a motorized stirrer.