I have some myself that I use of making vision blocks and the like, but I have some doubt that it will be able to produce a film large enough for a windshield. Basically, you use a brush, needle or other small, pointed tool and apply a bead of the product completely around the circumference of the opening where you want the window. Once the bead is in place, touch the tool to one edge of the goo and slowly pull it away. The product should "string" with the tool, forming a thin bubble or film. Pull this toward the far side of the opening and touch it to the bead on that side, if you are lucky, it will have pulled the film over the entire opening. It doesn't work every time. You might try to bend a piece of wire into an "L" that is just a bit shorter than the window is wide, then touch the whole length of the L into the goo, so that you pull a large amount away, producing a wide film, which you then anchor to the other side.
Hope this makes sense.
Or try Steve's way instead.....